The transformation is promoted by 3 7 mol of a cu complex generated in situ from a mixture of inexpensive cucl a readily available phosphine or imidazolium salt and kot bu at ambient temperature.
Copper vinyl sulfonate.
The central hexavalent sulfur atom is double bonded to each of two oxygen atoms and has a single bond to each of two carbon atoms usually in two separate hydrocarbon substituents.
Vinyl sulfonate esters are extremely good dienophiles cycloadditions occurring at much lower temperatures than their carboxylate counterparts.
A highly efficient and mild cu catalyzed conjugate addition reaction of aromatic amines and aromatic aza heterocycles to α β unsaturated olefins is described.
More buying choices 26 88 7 new offers copper sulfate crystals 99 8 minimum purity.
A sulfone is a chemical compound containing a sulfonyl functional group attached to two carbon atoms.
I ve been told that sodium allyl sulfonate sas and sodium vinyl sulfonate svs are used as brightening agents for nickel electroplating.
The propargyl sulfonates bearing nitro vinyl.
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Older names for this compound include blue vitriol bluestone vitriol of copper and roman vitriol.
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Metz has investigated the use of these dienophiles in the intramolecular diels alder reaction with cyclic dienes and furans to furnish the cyclic sulfonate esters in excellent yields scheme 162 the intermediate trienes often cannot be isolated as.
Figure 3b a cooperative copper catalysis may be involved in the reaction in which one copper reacts with propargyl sulfonate 1 to generate the copper allenylidene complex and the other binds to the difluoroenolate.
Copper ii sulfate also known as copper sulphate are the inorganic compounds with the chemical formula cu so 4 h 2 o x where x can range from 0 to 5 the pentahydrate x 5 is the most common form.
Copper sulfate pentahydrate crystals root killer destroyer 25 copper cu 100 water soluble greenway biotech brand 3 pounds 4 5 out of 5 stars 58 21 99 21.
Sigma aldrich offers a number of divinyl sulfone products.
A wide range of β amino sulfone.
View information documentation regarding divinyl sulfone including cas msds more.